{"id":14,"date":"2019-03-08T01:37:18","date_gmt":"2019-03-08T01:37:18","guid":{"rendered":"http:\/\/myweb.fiu.edu\/kbukhrya\/?page_id=14"},"modified":"2026-05-14T09:38:37","modified_gmt":"2026-05-14T09:38:37","slug":"publications","status":"publish","type":"page","link":"https:\/\/myweb.fiu.edu\/kbukhrya\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"\n

FIU:<\/strong><\/p>\n\n\n\n

44. L. Wang, G. Castro, O. Alkhamis, M. R. Gangireddy, K. V. Bukhryakov<\/strong>, N. R. Vinueza, and Y. Xiao,* A Selective, Class-Specific Aptamer for Fentanyl Analog Screening, 2026<\/strong>, submitted<\/em>.<\/p>\n\n\n\n

43. S. Hernandez, V. Krivovicheva, A. Sousa-Silva, Xavier Solans-Monfort, and K. V. Bukhryakov,*<\/strong> Toward Vanadium-Mediated Alkyne Metathesis, Chem. Sci., <\/em>2026<\/strong>, 17<\/em>, 9132 – 9137. DOI: 10.1039\/d6sc01683a<\/a><\/p>\n\n\n

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42.   C. Acosta, L. Rodriguez-Santiago,V. Krivovicheva,X. Solans-Monfort,* and K. V. Bukhryakov,*<\/strong> Synthesis of Low-Spin Fe(II) NHC Complexes and Their Computational Evaluations in the Context of Olefin Metathesis, Organometallics<\/em><\/em><\/em>,<\/em> 2025<\/strong>, 44, <\/em>2741\u20132748. DOI: 10.1021\/acs.organomet.5c00281<\/a><\/p>\n\n\n

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41. S. Aguero, V. Krivovicheva, M. R. Gangireddy, and K. V. Bukhryakov,*<\/strong> Evaluation of Steric and Electronic Parameters of NHCs on Vanadium Imido Alkylidenes for Olefin Metathesis, ACS Catal.<\/em>, 2025<\/strong>, 15<\/em><\/em>, 18326\u201318332. DOI: 10.1021\/acscatal.5c05494<\/a><\/p>\n\n\n

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40.   T. Nguyen, O. Alkhamis, A. K. Bacon, K. V. Bukhryakov<\/strong>, N. R. Vinueza, and Y. Xiao,* High-Contrast Aptamer-Based Merocyanine Displacement Assays for Sensitive Small Molecule Detection, ACS Sens<\/em>., 2025<\/strong>, 10<\/em>, 7799\u20137809. DOI: 10.1021\/acssensors.5c02194<\/a><\/p>\n\n\n

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39. R. K. Haridasan, S. Hernandez, S. Kuenzig, G. Tejeda, K. V. Bukhryakov,*<\/strong> K. Searles,* Silica-Supported Vanadium-Oxo-Alkylidene for Self-Metathesis of Propene, J. Am. Chem. Soc.<\/em>, 2025<\/strong>, 147, <\/em>36039\u201336043. DOI: 10.1021\/jacs.5c07854<\/a><\/p>\n\n\n

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38. V. Krivovicheva, M. R. Gangireddy, A. Liu, L. B. Maya, A. M. Mebel, and K. V. Bukhryakov<\/strong>,*<\/strong> Vanadium-Mediated Carbon Isotope Exchange of Terminal Alkenes, J. Am. Chem. Soc.<\/em>, 2025<\/strong>, 147, <\/em>20212\u201320217. DOI: 10.1021\/jacs.5c05880<\/a><\/p>\n\n\n

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37. S. Hernandez, D. S. Belov, V. Krivovicheva, S. Senthil, and K. V. Bukhryakov<\/strong>,*<\/strong> Decreasing the Bond Order Between Vanadium and Oxo Ligand to Form 3d Schrock Carbynes, J. Am. Chem. Soc.<\/em>, 2024<\/strong>, 146, <\/em>18905\u201318909. DOI: 10.1021\/jacs.4c07588<\/a><\/p>\n\n\n

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36. C. M. B. Bolding, T. K. Haraniya, G. L. Parker, W. B. Martin, V. G. Desyatkin, L. Heck, K. V. Bukhryakov<\/strong>, V. O. Rodionov,* Edge Functionalization of Bulk \u03b3-Graphyne Facilitates Mechanical Exfoliation and Modulates the Mode of Sheet Stacking, J. Am. Chem. Soc.<\/em>, 2024<\/strong>, 146<\/em>, <\/em>12889\u221212894. DOI: 10.1021\/jacs.4c02064<\/a><\/p>\n\n\n

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35. C. M. Acosta, D. S. Belov, A. H. Lamur, C. L. Brantley, X. Solans-Monfort, K. L. Rue, G. Christou, and K. V. Bukhryakov<\/strong>,*<\/strong> Mononuclear Four-Coordinate Bis-Fluoride Bis-NHC Complexes of Chromium(II), Iron(II), and Cobalt(II), Inorg. Chem.<\/em>, 2023<\/strong>, 62<\/em>, 18108\u201318115. DOI: 10.1021\/acs.inorgchem.3c02442<\/a><\/p>\n\n\n

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34. W. S. Farrell,* G. Tejeda, X. Solans-Monfort, \u00c9. S\u00e1, K. V. Bukhryakov<\/strong>, Ring-Opening Metathesis Polymerization with Vanadium(V) Alkylidenes: Survey of Initiators, Density-Functional Theory Calculations, and Functional Group Tolerance, J. Organomet. Chem., <\/em>2023<\/strong>, 996<\/em><\/em>, <\/em>122753. DOI: 10.1016\/j.jorganchem.2023.122753<\/a><\/p>\n\n\n

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33. D. S. Belov, C. Acosta, M. Garcia-Molina K. L. Rue, X. Solans-Monfort, and K. V. Bukhryakov<\/strong>,* Synthesis and Activity of Vanadium Oxo NHC Alkylidenes. Remarkable Preference for Degenerate Metathesis and Application for Carbon Isotope Exchange, Organometallics<\/em><\/em><\/em>, <\/em>2022<\/strong>, 41<\/em>, 2897\u20132902. DOI: 10.1021\/acs.organomet.2c00465<\/a><\/p>\n\n\n

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32. G. Tejeda, D. S. Belov, D. A. Fenoll, K. L. Rue, C. Tsay, X. Solans-Monfort, and K. V. Bukhryakov<\/strong>,* Vanadium Imido NHC Complexes for the Ring-Closing Olefin Metathesis Reactions, Organometallics<\/em><\/em><\/em>, 2022<\/strong>, 41<\/em>, 361-365. DOI: 10.1021\/acs.organomet.2c00013<\/a><\/p>\n\n\n

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31. O. Alkhamis, J. Canoura, K. V. Bukhryakov<\/strong>, A. Tarifa, A. P. DeCaprio, and Y. Xiao,* DNA Aptamer-Cyanine Complexes as Generic Colorimetric Small-Molecule Sensors, Angew. Chem., Int. Ed.,<\/em> 2021<\/strong>, 60<\/em>, 2-12. DOI: 10.1002\/anie.202112305<\/a><\/p>\n\n\n

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30. D. S. Belov, D. A. Fenoll, I. Chakraborty, X. Solans-Monfort, and K. V. Bukhryakov<\/strong>,* Synthesis of Vanadium Oxo Alkylidene Complex and its Reactivity in Ring-Closing Olefin Metathesis Reactions, Organometallics<\/em><\/em>, 2021<\/strong>, 40<\/em>, 2939\u20132944. DOI: 10.1021\/acs.organomet.1c00425<\/a><\/p>\n\n\n

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29. D. S. Belov, G. Tejeda, and K. V. Bukhryakov<\/strong>,* Olefin Metathesis by First-Row Transition Metals (invited review), ChemPlusChem<\/em>, 2021<\/strong>, 86<\/em>, 924-937. DOI: 10.1002\/cplu.202100192<\/a> <\/p>\n\n\n

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28. D. S. Belov, G. Tejeda, C. Tsay, and K. V. Bukhryakov<\/strong>,* Ring-Closing Olefin Metathesis Catalyzed by Well-Defined Vanadium Alkylidene Complexes, Chem. Eur. J<\/em>, 2021<\/strong>, 27<\/em>, 4578-4582. DOI: 10.1002\/chem.202005438<\/a><\/p>\n\n\n

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27. D. S. Belov, L. Mathivathanan, M. J. Beazley, W. B. Martin, and K. V. Bukhryakov<\/strong>,* Stereospecific Ring-Opening Metathesis Polymerization of Norbornene Catalyzed by Iron Complexes, Angew. Chem., Int. Ed.,<\/em> 2021<\/strong>, 60<\/em>, 2934-2938. DOI: 10.1002\/anie.202011150<\/a> (highlighted in ChemistryViews<\/a>).<\/p>\n\n\n

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26. S. Chuprun, C. M. Acosta, L. Mathivathanan, and K. V. Bukhryakov<\/strong>,* Molybdenum Benzylidyne Complexes for Olefin Metathesis Reactions, Organometallics, <\/em>2020<\/strong>, 39<\/em>, 3453-3457. DOI: 10.1021\/acs.organomet.0c00491<\/a><\/p>\n\n\n

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Before FIU<\/strong><\/p>\n\n\n\n

Postdoctoral research (MIT):<\/strong><\/p>\n\n\n\n

25. F. Zhai, K. V. Bukhryakov<\/strong>, R. R. Schrock, A. Hoveyda, C. Tsay, and P. M\u00fcller, Syntheses of Molybdenum \u041e\u0445\u043e Benzylidene Complexes, J. Am. Chem. Soc.<\/em>, 2018, <\/strong>140, <\/em>13609-13613. DOI: 10.1021\/jacs.8b09616<\/a><\/p>\n\n\n

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24. K. V. Bukhryakov<\/strong>, R. R. Schrock, A. Hoveyda, C. Tsay, and P. M\u00fcller, Syntheses of Molybdenum \u041e\u0445\u043e Alkylidene Complexes Through Addition of Water to an Alkylidyne Complex, J. Am. Chem. Soc.<\/em>, 2018<\/strong>, 140<\/em>, 2797-2800. DOI: 10.1021\/jacs.8b00499<\/a><\/p>\n\n\n

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23. K. V. Bukhryakov<\/strong>, S. VenkatRamani, C. Tsay, A. Hoveyda, and R. R. Schrock, Syntheses of Molybdenum Adamantylimido and t<\/em>-Butylimido Alkylidene Chloride Complexes Using HCl and Diphenylmethylphosphine, Organometallics, <\/em>2017<\/strong>, 36, <\/em>4208-4214. DOI: 10.1021\/acs.organomet.7b00647<\/a><\/p>\n\n\n

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22. P. E. Sues, K. V. Bukhryakov<\/strong>, and R. R. Schrock, Evaluation of Several Molybdenum and Ruthenium Catalysts for the Metathesis Homocoupling of 3-Methyl-1-Butene, Helv. Chim. Acta, <\/em>2017<\/strong>, 100<\/em>, e1700181. DOI: 10.1002\/hlca.201700181<\/a> <\/p>\n\n\n

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21. K. V. Bukhryakov<\/strong>, R. R. Schrock, A. Hoveyda, P. M\u00fcller, and J. Becker, Synthesis of 2,6-Hexatertiarybutylterphenyl Derivatives, 2,6-(2,4,6-t<\/em>-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2, Org. Lett.<\/em>, 2017<\/strong>, 19<\/em>, 2607-2609. DOI: 10.1021\/acs.orglett.7b01062<\/a> <\/p>\n\n\n

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20. J. K. Lam, C. Zhu, K. V. Bukhryakov<\/strong>, P. M\u00fcller, A. Hoveyda, and R. R. Schrock, Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z<\/em>-1,2- Dichloroethylene, J. Am. Chem. Soc.<\/em>, 2016<\/strong>, 138<\/em>, 15774-15783. DOI: 10.1021\/jacs.6b10499<\/a> <\/p>\n\n\n

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19. P. E. Sues, J. M. John, K. V. Bukhryakov<\/strong>, R. R. Schrock, and P. M\u00fcller, Molybdenum and Tungsten Alkylidene Complexes That Contain a 2-Pyridyl-substituted Phenoxide Ligand, Organometallics, <\/em>2016<\/strong>, 35<\/em>, 3587-3593. DOI: 10.1021\/acs.organomet.6b00644 <\/a><\/p>\n\n\n

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Postdoctoral research (KAUST): <\/strong><\/p>\n\n\n\n

18. T. Chen, B. Chen, K. V. Bukhryakov<\/strong>, and V. O. Rodionov, Thiols Make for Better Catalyst: Au Nanoparticles Supported on Functional SBA-15 for Catalysis of Ullmann-type Homocouplings, Chem. Commun.<\/em>, 2017<\/strong>, 53<\/em>, 11638-11641. DOI: 10.1039\/C7CC06146C<\/a> <\/p>\n\n\n

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17. K. B. Vu, T. Chen, S. Almahdali, K. V. Bukhryakov<\/strong>, and V. O. Rodionov, Hollow Nanospheres with Fluorous Interiors for Transport of Molecular Oxygen in Water, ChemistrySelect<\/em>, 2016<\/strong>, 1<\/em>, 3306-3309. DOI: 10.1002\/slct.201600602<\/a> <\/p>\n\n\n

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16. K. V. Bukhryakov<\/strong>, V. G. Desyatkin, and V. O. Rodionov, Cooperative Organocatalysis of Mukaiyama\u2013Type Aldol Reactions by Thioureas and Nitro Compounds, Chem. Commun.<\/em>, 2016<\/strong>, 52<\/em>, 7576-7579. DOI: 10.1039\/C6CC01984F<\/a> <\/p>\n\n\n

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15. C. Mugemana, K. V. Bukhryakov<\/strong>, O. Bertrand, K. B. Vu, J.-F. Gohy, N. Hadjichristidis, V. O. Rodionov, Ring opening metathesis polymerization of cyclopentene using a ruthenium catalyst confined by a branched polymer architecture, Polym. Chem., <\/em>2016<\/strong>, 7<\/em>, 2923-2928. DOI: 10.1039\/C6PY00389C<\/a> <\/p>\n\n\n

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14. K. V. Bukhryakov<\/strong>, C. Mugemana, K. B. Vu, V. O. Rodionov, Palladium-N-Heterocyclic Carbene Pre-Catalyst Site-Isolated in the Core of a Star Polymer, Org. Lett.<\/em>, 2015<\/strong>, 17<\/em>, 4826-4829 DOI: 10.1021\/acs.orglett.5b02388<\/a> (selected by the Editorial Board of Synfacts for its important insights, Synfacts<\/em>, 2016<\/strong>, 12<\/em>, 99 DOI: 10.1055\/s-0035-1561082<\/a>). <\/p>\n\n\n

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13. K. B. Vu, K. V. Bukhryakov<\/strong>, D. H. Anjum, V. O. Rodionov, Surface-Bound Ligands Modulate Chemoselectivity and Activity of a Bimetallic Nanoparticle Catalyst, ACS Catal.<\/em>, 2015<\/strong>, 5<\/em>, 2529-2533 (K. B. Vu and K. V. Bukhryakov <\/strong>contributed equally). DOI: 10.1021\/acscatal.5b00262<\/a> <\/p>\n\n\n

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12. K. V. Bukhryakov<\/strong>, S. Almahdali, and V. O. Rodionov, Amplification of Chirality through Self-Replication of Micellar Aggregates in Water, Langmuir<\/em>, 2015<\/strong>, 31<\/em>, 2931-2935. DOI: 10.1021\/la504984j<\/a> <\/p>\n\n\n

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11. B. Chen, K. V. Bukhryakov<\/strong>, R. Sougrat, and V. Rodionov, An Enzyme-Inspired Functional Surfactant for Aerobic Oxidation of Activated Alcohols to Aldehydes in Water, ACS Catal.<\/em>, 2015<\/strong>, 5<\/em>, 1313-1317. DOI: 10.1021\/cs5020018<\/a> <\/p>\n\n\n

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10. K. V. Bukhryakov<\/strong>, V. G. Desyatkin, J. P. O\u2019Shea, S. R. Almahdali, V. Solovyeva, and V. Rodionov, Cooperative Catalysis With Block Copolymer Micelles: A Combinatorial Approach, ACS Comb. Sci.<\/em>, 2015<\/strong>, 17<\/em>, 76-80 DOI: 10.1021\/co5001713<\/a> (selected as ACS Editors\u2019 Choice <\/strong>article, Jan. 13, 2015 and highlighted in C&EN<\/em><\/strong>, <\/em>Jan. 19, 2015) <\/p>\n\n\n

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9. C. Mugemana, B. Chen, K. V. Bukhryakov<\/strong>, and V. Rodionov, Star Block-Copolymers: Enzyme-Inspired Catalysts for Oxidation of Alcohols in Water, Chem. Commun.<\/em>, 2014<\/strong>, 50<\/em>, 7862-7865. DOI: 10.1039\/C4CC03370A<\/a> <\/p>\n\n\n

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Ph.D. research (MSU and CDI): <\/strong> <\/p>\n\n\n\n

8. K. V. Bukhryakov<\/strong>, A. V. Kurkin, M. A. Yurovskaya, Synthesis of Imidazo[4,5-b]pyridines with a Chiral Substituent at the Nitrogen Atom and their Conversion to Piperazine Derivatives, Chem. Heterocycl. Compd. (N.Y.)<\/em>, 2012<\/strong>, 48<\/em>, 773-784. DOI: 10.1007\/s10593-012-1056-5<\/a><\/p>\n\n\n

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7. K. V. Bukhryakov<\/strong>, A. V. Kurkin, and M. A. Yurovskaya, Synthetic Approaches to Imidazo[4,5-b<\/em>]pyridine Derivatives (review), Chem. Heterocycl. Compd. (N.Y.)<\/em>, 2011<\/strong>, 47<\/em>, 533-557. DOI: 10.1007\/s10593-011-0797-x<\/a> <\/p>\n\n\n\n

6. A. V. Kurkin, K. V. Bukhryakov<\/strong>, M. A. Yurovskaya, Synthesis of 1,2,3,4-tetrahydro[2,3-b<\/em>]pyrazindiones with a Chiral Substituent at the Nitrogen, Chem. Heterocycl. Compd. (N.Y.)<\/em>, 2009<\/strong>, 45<\/em>, 188-193. DOI: 10.1007\/s10593-009-0249-z<\/a><\/p>\n\n\n

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5. I. Konstantinov, K. Bukhryakov<\/strong>, Y. Gezentsvey, and M. Krasavin, Practical Method for Parallel Synthesis of Diversely Substituted 1-Phenylpiperazines, Lett. Org. Chem.<\/em>, 2011<\/strong>, 8<\/em>, 628-630. DOI: 10.2174\/157017811799304386<\/a> <\/p>\n\n\n

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4. M. Krasavin, V. Parchinsky, S. Shkavrov, and K. Bukhryakov<\/strong>, Applications of Quinoxaline Synthesis via Isocyanide-Based MCR. Multi-Component Reactions in Drug Discovery, Adv. Exp. Med. Bio<\/em>, 2011<\/strong>, 699<\/em>, 88-89. DOI: 10.1007\/978-1-4419-7270-5_3<\/a> <\/p>\n\n\n

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3. M. Krasavin, R. Karapetian, I. Konstantinov, Y. Gezentsvey, K. Bukhryakov<\/strong>, E. Godovykh, O. Soldatkina, Y. Lavrovsky, A.V. Sosnov, A.A. Gakh, Discovery and Potency Optimization of 2-Amino-5-arylmethyl-1,3-thiazole Derivatives as Potential Therapeutic Agents for Prostate Cancer, Arch. Pharm.<\/em>, 2009<\/strong>, 342<\/em>, 420-427. DOI: 10.1002\/ardp.200800201<\/a> <\/p>\n\n\n

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2. M. Krasavin, S. Shkavrov, V. Parchinsky, and K. Bukhryakov<\/strong>, Imidazo[1,2-a<\/em>]quinoxalines Accessed via Two Sequential Isocyanide-Based Multicomponent Reactions, J. Org. Chem.<\/em>, 2009<\/strong>, 74<\/em>, 2627-2629. DOI: 10.1021\/jo900050<\/a> <\/p>\n\n\n

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1.M. Krasavin, S. Tsirulnikov, M. Nikulnikov, Y. Sandulenko, and K. Bukhryakov<\/strong>, tert<\/em>-Butyl Isocyanide Revisited as a Convertible Reagent in the Groebke\u2013Blackburn Reaction, Tetrahedron Lett., <\/em>2008<\/strong>, 49<\/em>, 7318-7321. DOI: 10.1016\/j.tetlet.2008.10.046<\/a><\/p>\n\n\n

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\"\"<\/a><\/figure>\n<\/div>","protected":false},"excerpt":{"rendered":"

FIU: 44. L. Wang, G. Castro, O. Alkhamis, M. R. Gangireddy, K. V. Bukhryakov, N. R. Vinueza, and Y. Xiao,* A Selective, Class-Specific Aptamer for Fentanyl Analog Screening, 2026, submitted. 43. S. Hernandez, V. Krivovicheva, A. Sousa-Silva, Xavier Solans-Monfort, and K. V. Bukhryakov,* Toward Vanadium-Mediated Alkyne Metathesis, Chem. Sci., 2026, 17, 9132 – 9137. DOI: […]<\/p>\n","protected":false},"author":2434,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-14","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/pages\/14","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/users\/2434"}],"replies":[{"embeddable":true,"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/comments?post=14"}],"version-history":[{"count":0,"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/pages\/14\/revisions"}],"wp:attachment":[{"href":"https:\/\/myweb.fiu.edu\/kbukhrya\/wp-json\/wp\/v2\/media?parent=14"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}